ResearchSpace

Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications

Show simple item record

dc.contributor.author Musyoka, Nicholas M
dc.contributor.author Ren, Jianwei
dc.contributor.author Annamalai, P
dc.contributor.author Langmi, Henrietta W
dc.contributor.author North, Brian C
dc.contributor.author Mathe, Mahlanyane K
dc.contributor.author Cesar, D
dc.date.accessioned 2017-02-23T10:05:28Z
dc.date.available 2017-02-23T10:05:28Z
dc.date.issued 2016-06
dc.identifier.citation Musyoka, N.M., Ren, J., Annamalai, P., Langmi, H.W., North, B.C., Mathe, M. and Cesar, D. 2016. Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications. Research on Chemical Intermediates, 42(6), pp 5299–5307 en_US
dc.identifier.issn 0922-6168
dc.identifier.uri http://link.springer.com/article/10.1007/s11164-015-2361-2
dc.identifier.uri http://hdl.handle.net/10204/8986
dc.identifier.uri https://doi.org/10.1007/s11164-015-2361-2
dc.identifier.uri https://rdcu.be/b5O2a
dc.description Copyright: 2016 Springer. Due to copyright restrictions, the attached PDF file only contains the abstract of the full text item. For access to the full text item, please consult the publisher's website. The definitive version of the work is published in Research on Chemical Intermediates, 42(6), pp 5299–5307 en_US
dc.description.abstract Metal–organic frameworks (MOFs) hybrid composites have recently attracted considerable attention in hydrogen storage applications. In this study a hybrid composite of zeolite templated carbon (ZTC) and Cr-based MOF (MIL-101) was synthesised by adding the templated carbon in situ during the synthesis of MIL-101(Cr). The obtained sample was fully characterized and hydrogen adsorption measurements performed at 77 K up to 1 bar. The results showed that the surface areas and the hydrogen uptake capacities of individual MIL-101 (2552 m(sup2) g(sup-1), 1.91 wt%) and zeolite templated carbon (2577 m(sup2) g(sup-1), 2.39 wt%) could be enhanced when a hybrid MIL-101(Cr)/ZTC composite (2957 m(sup2) g(sup-1), 2.55 wt%) was synthesized. The procedure presents a simple way for enhancement of hydrogen uptake capacity of the individual Cr-MOF and templated carbon samples. en_US
dc.language.iso en en_US
dc.publisher Springer en_US
dc.relation.ispartofseries Wokflow;17805
dc.subject Metal organic framework en_US
dc.subject MOF en_US
dc.subject Zeolite templated carbon en_US
dc.subject ZTC en_US
dc.subject (Cr)/ZTC en_US
dc.subject Hydrogen uptake en_US
dc.subject Surface area en_US
dc.title Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications en_US
dc.type Article en_US
dc.identifier.apacitation Musyoka, N. M., Ren, J., Annamalai, P., Langmi, H. W., North, B. C., Mathe, M. K., & Cesar, D. (2016). Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications. http://hdl.handle.net/10204/8986 en_ZA
dc.identifier.chicagocitation Musyoka, Nicholas M, Jianwei Ren, P Annamalai, Henrietta W Langmi, Brian C North, Mahlanyane K Mathe, and D Cesar "Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications." (2016) http://hdl.handle.net/10204/8986 en_ZA
dc.identifier.vancouvercitation Musyoka NM, Ren J, Annamalai P, Langmi HW, North BC, Mathe MK, et al. Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications. 2016; http://hdl.handle.net/10204/8986. en_ZA
dc.identifier.ris TY - Article AU - Musyoka, Nicholas M AU - Ren, Jianwei AU - Annamalai, P AU - Langmi, Henrietta W AU - North, Brian C AU - Mathe, Mahlanyane K AU - Cesar, D AB - Metal–organic frameworks (MOFs) hybrid composites have recently attracted considerable attention in hydrogen storage applications. In this study a hybrid composite of zeolite templated carbon (ZTC) and Cr-based MOF (MIL-101) was synthesised by adding the templated carbon in situ during the synthesis of MIL-101(Cr). The obtained sample was fully characterized and hydrogen adsorption measurements performed at 77 K up to 1 bar. The results showed that the surface areas and the hydrogen uptake capacities of individual MIL-101 (2552 m(sup2) g(sup-1), 1.91 wt%) and zeolite templated carbon (2577 m(sup2) g(sup-1), 2.39 wt%) could be enhanced when a hybrid MIL-101(Cr)/ZTC composite (2957 m(sup2) g(sup-1), 2.55 wt%) was synthesized. The procedure presents a simple way for enhancement of hydrogen uptake capacity of the individual Cr-MOF and templated carbon samples. DA - 2016-06 DB - ResearchSpace DP - CSIR KW - Metal organic framework KW - MOF KW - Zeolite templated carbon KW - ZTC KW - (Cr)/ZTC KW - Hydrogen uptake KW - Surface area LK - https://researchspace.csir.co.za PY - 2016 SM - 0922-6168 T1 - Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications TI - Synthesis of a hybrid MIL-101(Cr)/ZTC composite for hydrogen storage applications UR - http://hdl.handle.net/10204/8986 ER - en_ZA


Files in this item

Thumbnail
Name: Musyoka_2016_ABST ...
Size: 71.50Kb
Format: PDF
View/Open

This item appears in the following Collection(s)

Show simple item record