dc.contributor.author |
Kebede, Mesfin A
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|
dc.contributor.author |
Zheng, Haitao
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|
dc.contributor.author |
Ozoemena, KI
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dc.date.accessioned |
2017-02-23T10:04:53Z |
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dc.date.available |
2017-02-23T10:04:53Z |
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dc.date.issued |
2016-07 |
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dc.identifier.citation |
Kebede, M., Zheng, H. and Ozoemena, K.I. 2016. Metal oxides and lithium alloys as anode materials for lithium-ion batteries. In: Nanomaterials in Advanced Batteries and Supercapacitors, Springer International Publishing: New York, USA, pp 55-91 |
en_US |
dc.identifier.isbn |
978-3-319-26080-8 |
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dc.identifier.uri |
http://link.springer.com/chapter/10.1007%2F978-3-319-26082-2_3
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|
dc.identifier.uri |
http://hdl.handle.net/10204/8980
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|
dc.description |
Copyright: Springer International Publishing: New York, USA. Due to copyright restrictions, the attached PDF file only contains the abstract of the full text item. For access to the full text item, please consult the publisher's website. |
en_US |
dc.description.abstract |
Metal oxides such as TiO(sub2), Li(sub4)Ti(sub5)O(sub12), SnO(sub2), SnO, M(sub2)SnO(sub4) (M=ZnM=Zn, Co, Mn, Mg), TMO (TM=MnTM=Mn, Fe, Co, Ni, or Cu), TM(sub3)O(sub4) (TM=CoTM=Co, Fe, or Mn), and lithium alloys Li–Sn, Li–Si are among the next-generation anode materials for lithium–ion batteries with high prospect of replacing graphite. Most of these anode materials have higher specific capacities between the range of 600-1000 mA h g(sup-1) compared with 340 mA h g(sup-1) of graphite. These high-capacity anode materials normally face poor cycle performance due to severe volume change during the discharge/charge reactions which leads to crack and pulverization. To overcome these limitations, two commonly adopted strategies are nano-engineering and coating with carbon. In this chapter, we have discussed the metal oxides and lithium alloy anodes in three sections, with emphasis on their electrochemical reaction mechanisms with lithium. We have also presented a brief historical review based on the development of the metal oxides and lithium alloys as anode materials for lithium–ion battery, highlighted ongoing research strategies, and discussed the challenges that remain regarding the synthesis, characterization, and electrochemical performance of the materials. |
en_US |
dc.language.iso |
en |
en_US |
dc.publisher |
Springer |
en_US |
dc.relation.ispartofseries |
Wokflow;17801 |
|
dc.subject |
Li-ion batteries |
en_US |
dc.subject |
Anode materials |
en_US |
dc.subject |
Metal oxides |
en_US |
dc.subject |
Intercalation |
en_US |
dc.subject |
Alloying |
en_US |
dc.subject |
Dealloying |
en_US |
dc.subject |
Conversion(redox) |
en_US |
dc.subject |
Lithium alloys |
en_US |
dc.subject |
Nanostructures |
en_US |
dc.subject |
Carbon coating |
en_US |
dc.title |
Metal oxides and lithium alloys as anode materials for lithium-ion batteries |
en_US |
dc.type |
Book Chapter |
en_US |
dc.identifier.apacitation |
Kebede, M. A., Zheng, H., & Ozoemena, K. (2016). Metal oxides and lithium alloys as anode materials for lithium-Ion batteries., <i>Wokflow;17801</i> Springer. http://hdl.handle.net/10204/8980 |
en_ZA |
dc.identifier.chicagocitation |
Kebede, Mesfin A, Haitao Zheng, and KI Ozoemena. "Metal oxides and lithium alloys as anode materials for lithium-ion batteries" In <i>WOKFLOW;17801</i>, n.p.: Springer. 2016. http://hdl.handle.net/10204/8980. |
en_ZA |
dc.identifier.vancouvercitation |
Kebede MA, Zheng H, Ozoemena K. Metal oxides and lithium alloys as anode materials for lithium-ion batteries.. Wokflow;17801. [place unknown]: Springer; 2016. [cited yyyy month dd]. http://hdl.handle.net/10204/8980. |
en_ZA |
dc.identifier.ris |
TY - Book Chapter
AU - Kebede, Mesfin A
AU - Zheng, Haitao
AU - Ozoemena, KI
AB - Metal oxides such as TiO(sub2), Li(sub4)Ti(sub5)O(sub12), SnO(sub2), SnO, M(sub2)SnO(sub4) (M=ZnM=Zn, Co, Mn, Mg), TMO (TM=MnTM=Mn, Fe, Co, Ni, or Cu), TM(sub3)O(sub4) (TM=CoTM=Co, Fe, or Mn), and lithium alloys Li–Sn, Li–Si are among the next-generation anode materials for lithium–ion batteries with high prospect of replacing graphite. Most of these anode materials have higher specific capacities between the range of 600-1000 mA h g(sup-1) compared with 340 mA h g(sup-1) of graphite. These high-capacity anode materials normally face poor cycle performance due to severe volume change during the discharge/charge reactions which leads to crack and pulverization. To overcome these limitations, two commonly adopted strategies are nano-engineering and coating with carbon. In this chapter, we have discussed the metal oxides and lithium alloy anodes in three sections, with emphasis on their electrochemical reaction mechanisms with lithium. We have also presented a brief historical review based on the development of the metal oxides and lithium alloys as anode materials for lithium–ion battery, highlighted ongoing research strategies, and discussed the challenges that remain regarding the synthesis, characterization, and electrochemical performance of the materials.
DA - 2016-07
DB - ResearchSpace
DP - CSIR
KW - Li-ion batteries
KW - Anode materials
KW - Metal oxides
KW - Intercalation
KW - Alloying
KW - Dealloying
KW - Conversion(redox)
KW - Lithium alloys
KW - Nanostructures
KW - Carbon coating
LK - https://researchspace.csir.co.za
PY - 2016
SM - 978-3-319-26080-8
T1 - Metal oxides and lithium alloys as anode materials for lithium-ion batteries
TI - Metal oxides and lithium alloys as anode materials for lithium-ion batteries
UR - http://hdl.handle.net/10204/8980
ER -
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en_ZA |